It seems that A6 is still an input, but by default it is mapped as a DAC
From the (new) documentation:
A0~A7
12-bit Analog-to-Digital (A/D) inputs (0-4095), and also digital GPIOs. A6 and A7 are code convenience mappings, which means pins are not actually labeled as such but you may use code like analogRead(A7). A6 maps to the DAC pin and A7 maps to the WKP pin.
No, there is no option to reassign 3V3* to VBAT, but it’s perfectly acceptable (even recommended) to bridge 3V3 to VBAT as long you don’t use VBAT for its original purpose (a decoupling cap would also be good to use)