Help with setting Photon Schedules

I'm not sure what you mean by that. You create an alarm with a specific time, and a function that is executed when the alarm times out,

Alarm.alarmRepeat(17,45,10,onAlarm);  // Execute onAlarm at 5:45pm every day 
Alarm.alarmRepeat(18,45,10,offAlarm); // Execute offAlarm at 6:45pm every day 

void  loop(){}


void onAlarm(){
  // do whatever you want to happen at 5:45 PM  (like digitalWrite(led1, HIGH))        
}

void offAlarm(){
  // do whatever you want to happen at 6:45 PM  (like digitalWrite(led1, LOW))           
}
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